One of the beauties of LiFePO4 batteries is that they accept a battery charge far more rapidly than AGM or FLA batteries.
I have always used a dedicated Li battery charger--in the case of the c Dory it was the Multiplus 2000 watt inverter which has an 80 amp charger built in. I have several other set ups: one for the SUVs for frozen food / long trip food--and use a 10 amp Li Battery charger for that 100 amp battery. I have a 6 bank 100 amp battery, with solar panels, and if I need to top those off, I use the same 10 amp charger, although I have a number of other chargers, mostly for FLE. I do have one 30 amp charger which I have used which has an AGM profile.
The Guest charger could charge the Li bank, and probably would get it close to full charge, but you would want to take it off at that point. Almost all of the current LiFePO4 batteries have a good BMS internal system, which will prevent overcharging, which could be a danger. Even with my dedicated 10 amp charger, I only leave it on until the batteries are fully charged (which means topped of, because the self discharge rate is so low).
Which DC to DC charger are you using? What is the state of charge of the Li bank, when you are at the end of a voyage and get home? How are you monitoring the Li bank? What is the reason you went to LI (use of inverter, CPAC, etc?--more than just house loads?).
Most days run, even with only the 30 amps we were using from the Honda 150, (limited by DC to DC charger) we almost always had full batteries at the end of a day's run. We did use the 80 amp charger at times when we had not run the engine for a day. Our used for the Li was Inverter to run microwave and induction burner, plus two chest freezer/refrigerator units. We still had a single group 31 for the lights, navigation etc. However we had a swith which could change that to the Li battery bank (NOT parallel the two banks). Monitor with Victron monitor and the MFD for the Mulitplus inverter.
If we did not run the engine, then we used a Honda Generator to run the battery charger on the Multiplus inverter (usually combined with running the induction burner, or the microwave.