My appologies, I missed that there was a starting battery and house battery--thus two batteries already. Never the less, you can still get by with paralleling the two house batteries of different ages. What is the "risk"--boiling off electrolyte? Since the batteries are the same size and only different ages, there will be some difference, but as long as you watch the water, I doubt that there will be any problem, since the TC10TB is a 3 stage charger, when it goes into float charge, the difference in battery voltage will be minimal, and it will not be in a mode where there is a risk of boiling off electrolyte.
In reality when you have two batteries which are always in parallel, they are always at the same voltage (maybe you loose a slightly amount of capacity of the newer battery)--but there is no danger. It is not as if you have one battery at 13.8 volts and another battery which is at 11 volts, and high current flows when you connect them---that is a much different situation.
There was a long thread on THT about mixing batteries--and this can be done for charging also--as long as the voltages are compatable and charging characteristics are similar.
The Xantrex TC 10 TB is similar to the TC 20 and 40 chargers and in the float stage has a very low current flow, if any.
This is a chance to do an experiment. Put the old battery on the charger for 3 days, and then the new battery on the charger for 3 days. Take the battery off the charger and measure the voltage (to .01 places).. at 12 hours after you disconnect the charge. Compare the two batteries. My suspecian is that you will only see a few hundredths of a volt difference. If this is the case, it would be interesting to see how much current flows from one battery to the other--There might be a small amount initially, but after they have been connected for several hours, taken apart, and then reconnected.